According to Fajan's rules, which of the following conditions favors the formation of a covalent bond? MCQ with Answer and Explanation

According to Fajan's rules, which of the following conditions favors the formation of a covalent bond?
A. Large cation and small anion
B. Small cation and small anion
C. Large cation and large anion
D. Small cation and large anion
Answer: Option D
Solution (By JKExamLibrary)
Fajan's rules state that covalent character in an ionic bond increases with greater polarizing power of the cation and greater polarizability of the anion. A small cation has high charge density (high polarizing power), and a large anion has loosely held outer electrons (high polarizability), favoring covalency.

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Question #1
Which of the following represents a disproportionation reaction?
A. CaCO3 -> CaO + CO2
B. 2H2O2 -> 2H2O + O2
C. N2 + 3H2 -> 2NH3
D. Zn + CuSO4 -> ZnSO4 + Cu

Correct Answer: Option B


Explanation:
A disproportionation reaction is a specific type of redox reaction where the same element in a single substance is simultaneously oxidized and reduced. In the decomposition of hydrogen peroxide (H2O2), oxygen has an oxidation state of -1. It is reduced to -2 in H2O and oxidized to 0 in O2.

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Question #2
Which of the following changes is a physical change?
A. Burning of coal
B. Curdling of milk
C. Boiling of water
D. Rusting of iron

Correct Answer: Option C


Explanation:
Boiling water changes state from liquid to gas, but the chemical composition (H₂O) remains unchanged – physical change. Others form new substances.

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Question #3
Ethanol is used as a fuel additive. The complete combustion of ethanol yields:
A. CO and H₂
B. CO₂ and H₂
C. CO and H₂O
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Correct Answer: Option D


Explanation:
Complete combustion of ethanol: C₂H₅OH + 3O₂ → 2CO₂ + 3H₂O + heat. In sufficient oxygen, carbon burns to CO₂, hydrogen to H₂O. Incomplete combustion (lack of O₂) produces CO and soot (C). Ethanol is a biofuel, reducing CO₂ emissions if derived from biomass. It has high octane number and is blended with petrol (gasohol). CO₂ is a greenhouse gas, but bioethanol is carbon-neutral over cycle.

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