In the extraction of aluminium from bauxite, the reagent used to remove silica as an impurity is: MCQ with Answer and Explanation

In the extraction of aluminium from bauxite, the reagent used to remove silica as an impurity is:
A. Cl₂
B. NaOH
C. HCl
D. CO
Answer: Option B
Solution (By JKExamLibrary)
Bauxite contains SiO₂ (silica) as impurity. In the Bayer's process, powdered bauxite is treated with hot concentrated NaOH solution. Alumina dissolves forming sodium aluminate (NaAlO₂), while silica does not dissolve and is filtered off. Alternatively, silica can be removed by adding lime during refining. The purified alumina is then electrolyzed in cryolite. NaOH selectively dissolves Al₂O₃ due to its amphoteric nature.

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Question #1
Assertion (A): Methanol is highly toxic and can cause blindness if ingested. Reason (R): Methanol is metabolized in the body to formaldehyde and formic acid.
A. Both A and R are true but R is NOT the correct explanation of A.
B. A is false but R is true.
C. A is true but R is false.
D. Both A and R are true and R is the correct explanation of A.

Correct Answer: Option D


Explanation:
Methanol (wood alcohol) is highly toxic. When ingested, it is metabolized by the enzyme alcohol dehydrogenase into formaldehyde and then formic acid. Formic acid interferes with mitochondrial function, leading to metabolic acidosis, optic nerve damage, and blindness. Both statements are correct and R explains A.

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Question #2
Which of the following elements is NOT a p-block element?
A. Tin
B. Bismuth
C. Gallium
D. Zinc

Correct Answer: Option D


Explanation:
The p-block includes elements from groups 13 to 18. Gallium (Group 13), Tin (Group 14), and Bismuth (Group 15) are all p-block elements. Zinc (Group 12) has a completely filled d-subshell (3d10) in its ground state and common oxidation states, placing it in the d-block.

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Question #3
Cement sets under water because of:
A. Evaporation
B. Polymerization
C. Hydration and hydrolysis of calcium silicates
D. Oxidation

Correct Answer: Option C


Explanation:
Cement sets by hydration reactions forming C-S-H gel and Ca(OH)₂, even underwater. It's a chemical process, not drying. Gypsum controls the setting rate.

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