Temporary hardness of water is due to the presence of bicarbonates of calcium and magnesium. Boiling precipitates: MCQ with Answer and Explanation

Temporary hardness of water is due to the presence of bicarbonates of calcium and magnesium. Boiling precipitates:
A. CaCl₂
B. MgCl₂
C. CaSO₄
D. CaCO₃
Answer: Option D
Solution (By JKExamLibrary)
On boiling, soluble calcium bicarbonate decomposes: Ca(HCO₃)₂ → CaCO₃↓ + H₂O + CO₂. The precipitate is calcium carbonate (limestone/chalk). Magnesium bicarbonate similarly forms MgCO₃ or Mg(OH)₂. This removes Ca²⁺ and Mg²⁺ ions, softening the water. Permanent hardness (CaSO₄, CaCl₂) doesn't precipitate on boiling and needs chemical treatment.

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