PVC's rigidity in its unplasticized form is due to: MCQ with Answer and Explanation

PVC's rigidity in its unplasticized form is due to:
A. Covalent cross-links
B. Polar C-Cl bonds causing intermolecular attractions
C. Strong hydrogen bonding
D. High molecular weight only
Answer: Option B
Solution (By JKExamLibrary)
PVC has polar C-Cl bonds; the chlorine atoms create dipole-dipole interactions between polymer chains, restricting chain movement and making the material rigid and strong. Adding plasticizers (e.g., phthalates) reduces intermolecular forces, making it flexible. Cross-links are in thermosets, PVC is thermoplastic. High molecular weight contributes but polarity is key.

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Practice More chemistry Questions

Question #1
Which of the following is NOT a method of water purification?
A. Filtration
B. Electrolysis
C. Chlorination
D. Boiling

Correct Answer: Option B


Explanation:
Electrolysis of water decomposes it into hydrogen and oxygen, not purification. Boiling kills microbes, filtration removes particulate matter, chlorination disinfects. Other methods: UV treatment, ozonation, reverse osmosis, distillation. Electrolysis is a chemical decomposition technique.

This question belongs to: Science chemistry
Question #2
The property of carbon to form bonds with itself is called:
A. Tetravalency
B. Polymerisation
C. Isomerism
D. Catenation

Correct Answer: Option D


Explanation:
Catenation is the ability of carbon atoms to form long chains, rings, and networks via covalent bonds. This leads to a vast number of organic compounds. Silicon also catenates but to lesser extent.

This question belongs to: Science chemistry
Question #3
Which catalyst is used in the hydrogenation of vegetable oils?
A. Ni
B. Pt
C. V₂O₅
D. Fe

Correct Answer: Option A


Explanation:
Nickel (finely divided) is used as a catalyst in the hydrogenation of unsaturated vegetable oils to saturated fats (vanaspati ghee). The reaction adds H₂ across double bonds. Platinum and palladium are also hydrogenation catalysts but nickel is cheaper and industrially preferred. Fe is used in Haber process for ammonia synthesis, V₂O₅ in contact process for H₂SO₄. Catalysts provide an alternative pathway with lower activation energy.

This question belongs to: Science chemistry